Finding George Bailey: Wonderful leaders, wonderful lives

He is underpaid and overworked, his organization lives from payroll to payroll with an overtaxed and underpowered staff and a contentious board of directors. He sacrifices for the mission, but is frustrated about forgone personal dreams. He is George Bailey, the central character in Frank Capra\u27s film It\u27s a Wonderful Life and he practices Leadership for Good by being a mission centered, visionary, results driven, and adaptive difference maker. Through a construct-building non-generalizable mixed methods study with two concurrent, but independent phases—instrumental case study and Delphi—this study searched for real-life Baileys, to test whether or not Leadership for Good extends beyond the silver screen, to see whether or not life imitates art. The results supported all five propositions, although certain elements within the propositions were refuted and new elements substantiated. In addition to gaining a deeper understanding of the Leadership for Good construct, enriching the literature about nonprofit leadership, and reinforcing the usefulness of mixed methods research including Delphi technique, the study suggested that there were two primary types of leaders—those with a bias for growth and those with a bias for execution—who delivered equally superior financial results to the bottom line. As part of this finding, it appeared that these leaders practiced situational leadership in the here-and-now, but used contingency leadership over the long run to gravitate to preferred contexts—growth or execution—that corresponded roughly to periods of evolution and revolution. Other implications of the study were the reinforcement of the centrality of mission at the personal and organization levels, a more comprehensive understanding about what causes stress for those who practice Leadership for Good, and the ways in which leaders think about change. The electronic version of this dissertation is accessible at the OhioLINK ETD Center, https://etd.ohiolink.edu

Bromostibine complexes of iron(II): hypervalency and reactivity

The halostibine complexes [CpFe(CO)2(SbMe2Br)][CF3SO3] and [CpFe(CO)2(SbMe2Br)][BF4] both contain significant interactions between the anion and the formally neutral Sb(III) ligand, which simultaneously displays Lewis acidic and Lewis basic properties. The unexpected secondary product [CpFe(CO)(Me2BrSb-?-Br-SbBrMe2)] is formed in the presence of excess ligand, the strongly associated Br– anion bridging the two Sb donors to form a four-membered FeSb2Br ring.<br/

Impact of computer technology at McNeel Middle School

Includes bibliographical references

Synergistic catalysis: cis-cyclopropanation of benzoxazoles

In the present paper we report our latest efforts in pushing the boundaries of Synergistic Catalysis. We propose the use of 3 different catalytic cycles working in concert for the formation of cis cyclopropane derivatives of benzoxazoles with excellent stereoselectivities. This is the proof of concept that synergistic catalysis could be successfully used in cascade reaction

STEAM on the Quad

STEAM on the Quad is a family-oriented educational program, initiated in 2016, involving K-12 youth. Participants are able to do hands-on activities that improve their knowledge and interest in the science, technology, engineering, arts and math fields. The event is a collaborative project between Ohio State – Lima and OSU Extension. The 4-H programs of Putnam, Hardin and Allen counties hosted activities that featured Bluetooth sports, circuitry, Lego zip lines, virtual reality, graphics tablets, solar panels, sculpture building, hovercrafts and sewing. Community partners included the Allen County Soil and Water Conservation District, ArtSpace/Lima, YWCA Child Care, the Neil Armstrong Museum, and the Lima YMCA Bean City Bots Robotics Team. Ohio State – Lima faculty from biology, education, engineering, geology, and theater engaged K-12 students and their families in a variety of hands-on projects, as did Ohio State law enforcement. Ohio State staff and students aided in these endeavors and in logistical support. Outcomes and Impacts: 1) Connect local families, faculty, educators, and businesses to promote STEAM education through innovation, learning, and creativity in collaboration with Ohio State. 2) Take Ohio State's current resources and equipment and create programming that reaches new audiences, while bringing local 4-H members to an Ohio State campus. 3) Create a program model that can be reproduced by Extension in Ohio and other states. Outcomes and impacts will consist of recording the attendance and partnerships created through the STEAM programming, categorized by age group, program area, and type of use. Each student will complete a retrospective pre- and post-survey to see if our key STEM metrics are met. Finally, program evaluations will illustrate usage by parents and will collect open-ended feedback about how the STEAM programming has benefited their child. Quarterly progress reports will be provided to the university.AUTHOR AFFILIATION: Kelly Coble, Educator, 4-H Youth Development, The Ohio State University Extension, Allen County, [email protected] (Corresponding Author); Jason Hedrick, Educator, 4-H Youth Development, The Ohio State University Extension, Putnam County; Mark Light, Educator, 4-H Youth Development, The Ohio State University Extension, Hardin County; Amanda Raines, Program Assistant, 4-H Youth Development, The Ohio State University Extension, Hardin County; Sarah Jackson, Program Assistant, 4-H Youth Development, The Ohio State University Extension, Allen County.STEAM on the Quad is a family-oriented educational program, initiated in 2016, involving K-12 youth. Participants did hands-on activities that improved their knowledge and interest in the science, technology, engineering, arts and math fields. The event is a collaborative project between Ohio State – Lima and OSU Extension. The 4-H programs of Putnam, Hardin and Allen counties hosted activities that featured Bluetooth sports, Lego zip lines, virtual reality, graphics tablets, solar panels, sculpture building, hovercrafts and sewing. Community partners included the Allen County Soil and Water Conservation District, ArtSpace/Lima, YWCA Child Care, the Neil Armstrong Museum, and the Lima YMCA Bean City Bots robotics team. Ohio State – Lima faculty from biology, education, engineering, and theater engaged K-12 students and their families in a variety of hands-on projects, as did Ohio State law enforcement. Ohio State staff and students aided in these actvities and logistical support

National Crystallography Service (NCS) Grid Service

Conference poster about the NCS Grid Service.The EPSRC funded National Crystallography Service (NCS) is a facility available to the entire UK academic Chemistry community. The EPSRC funds a team of experts and 'state of the art' instrumentation, based in Southampton University School of Chemistry, to provide this service. This is an exceptionally important service as crystal structure determination is easily the most information rich method of characterisation of a compound and many research papers cannot be published without confirmation of identity by crystal structure analysis

Positive Youth Development in the 21st Century: Exploring Online Environments

The manner that young people and adults are communicating with each other is rapidly changing in society that is, in part, driven by the latest technology. As a youth-driven program, we must engage in new strategies and methods by which we communicate with youth members, volunteers, families, and the community at large. Social and mobile media are a growing and popular venue for much of our target audience and youth development practitioners must learn how to leverage these networks to create positive youth development in online environments. If we ignore and don’t engage in the opportunity to be connected to youth online, then youth are left to make their own paths online and set the online norms. As youth organizations, we also must seize the opportunity to be online mentors and use the resources that are available and being used by our target populations

Hexafluorosilicate and tetrafluoroborate coordination to lead(II) di- and tri-imine complexes – Unusual fluoroanion coordination modes

AbstractLead(II) tetrafluoroborate and hexafluorosilicate complexes with 2,2′-bipyridyl, 1,10-phenathroline and 2,2′:6′,2″-terpyridyl have been prepared from the ligand and lead salt in aqueous/MeCN. Crystal structures are reported for [Pb(bipy)2(SiF6)], [Pb(phen)2(SiF6)] and [Pb(bipy)2(BF4)2] which are dinuclear with each lead coordinated “cis” to the two diimines and with the bridging fluoroanions completing eight or nine-coordination. [Pb(phen)2(BF4)2] is eight-coordinate and mononuclear with “cis” diimines and two κ2-BF4− groups. [Pb(phen)2(H2O)2(SiF6)] is also mononuclear with a κ2-SiF62− group and two coordinated water molecules. Reaction of Pb(BF4)2 with 2,2′:6′,2″-terpyridyl gave only [Pb(terpy)3][BF4]2, but Pb(SiF6) produced [Pb(terpy)(H2O)(SiF6)], which is a chain polymer with bridging SiF62− groups and significant π-stacking of the imine rings. The work has identified a number of coordination modes of the SiF62− anion, which has been little used in coordination chemistry but proves to be versatile and also stable (to decomposition/hydrolysis)

Characterization of neurophysiologic and neurocognitive biomarkers for use in genomic and clinical outcome studies of schizophrenia.

BackgroundEndophenotypes are quantitative, laboratory-based measures representing intermediate links in the pathways between genetic variation and the clinical expression of a disorder. Ideal endophenotypes exhibit deficits in patients, are stable over time and across shifts in psychopathology, and are suitable for repeat testing. Unfortunately, many leading candidate endophenotypes in schizophrenia have not been fully characterized simultaneously in large cohorts of patients and controls across these properties. The objectives of this study were to characterize the extent to which widely-used neurophysiological and neurocognitive endophenotypes are: 1) associated with schizophrenia, 2) stable over time, independent of state-related changes, and 3) free of potential practice/maturation or differential attrition effects in schizophrenia patients (SZ) and nonpsychiatric comparison subjects (NCS). Stability of clinical and functional measures was also assessed.MethodsParticipants (SZ n = 341; NCS n = 205) completed a battery of neurophysiological (MMN, P3a, P50 and N100 indices, PPI, startle habituation, antisaccade), neurocognitive (WRAT-3 Reading, LNS-forward, LNS-reorder, WCST-64, CVLT-II). In addition, patients were rated on clinical symptom severity as well as functional capacity and status measures (GAF, UPSA, SOF). 223 subjects (SZ n = 163; NCS n = 58) returned for retesting after 1 year.ResultsMost neurophysiological and neurocognitive measures exhibited medium-to-large deficits in schizophrenia, moderate-to-substantial stability across the retest interval, and were independent of fluctuations in clinical status. Clinical symptoms and functional measures also exhibited substantial stability. A Longitudinal Endophenotype Ranking System (LERS) was created to rank neurophysiological and neurocognitive biomarkers according to their effect sizes across endophenotype criteria.ConclusionsThe majority of neurophysiological and neurocognitive measures exhibited deficits in patients, stability over a 1-year interval and did not demonstrate practice or time effects supporting their use as endophenotypes in neural substrate and genomic studies. These measures hold promise for informing the "gene-to-phene gap" in schizophrenia research

Aza-macrocyclic complexes of Group 1 cations:synthesis, structures and density functional theory study

The Group 1 complexes, [M(Me6[18]aneN6)][BArF] (M = Li–Cs; Me6[18]aneN6 = 1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane; BArF = tetrakis{3,5-bis(trifluoromethyl)-phenyl}borate), are obtained in high yield by reaction of the macrocycle with M[BArF] in anhydrous CH2Cl2 solution, and characterised spectroscopically (1H, 13C{1H}, 7Li, 23Na, and 133Cs NMR), by microanalysis and, for M = Li, K, and Rb, by single crystal X-ray analysis. The structures show N6-coordination to the metal ion; the small ionic radius for Li+ leads to a puckered conformation. In contrast, the K+ ion fits well into the N6 plane, with the [BArF]? anions above and below, leading to two K+ species in the asymmetric unit (a hexagonal planar [K(Me6[18]aneN6)]+ cation and a ‘[K(Me6[18]aneN6)(?1-BArF)2]? anion’, with long axial K?F interactions). The Rb+ ion sits above the N6 plane, with two long axial Rb?F interactions in one cation and two long, mutually cis Rb?F interactions in the other. The unusual sandwich cations, [M(Me3tacn)2]+ (M = Na, K; distorted octahedral, N6 donor set) and half-sandwich cations [Li(Me3tacn)(thf)]+ (distorted tetrahedron, N3O donor set), [Li(Me4cyclen)(OH2)]+, and [Na(Me4cyclen)(thf)]+ (both distorted square pyramids with N4O donor sets) were also prepared (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane, Me4cyclen = 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane). Density functional theory (DFT) calculations, using the BP86 and B3LYP functionals, show that the accessibility of the [M(Me3tacn)2]+ sandwich cations depends strongly on the M+ ionic radius, such that it is sufficiently large to avoid steric clashing between the Me groups of the two rings, and small enough to avoid very acute N–M–N chelate angles. The calculations also show that coordination to the Group 1 cation involves significant donation of electron density from the p-orbitals on the N atoms of the macrocycle, rather than purely electrostatic interactions